Lithium-salt conversion from lithium sulfate to lithium hydroxide

II. BPED — bipolar membrane electrodialysis (BMED) application scenario samples

2.1 Preparation of lithium hydroxide with bipolar membranes

Technical route: after lithium batteries are dismantled, sulfuric acid is used for dissolution to form lithium sulfate, which then enters resin to remove multivalent ions and meet the feedwater quality requirements for bipolar membranes. The bipolar membrane process produces sulfuric acid and lithium hydroxide.

Principle overview:

BPM (bipolar membrane) dissociates water inside the membrane into H⁺ and OH⁻

The feed solution is fed into the cathode chamber and anode chamber, respectively

In the middle C/A chamber, H⁺, OH⁻, and SO₄²⁻ ions migrate directionally under the electric field

The outlets produce H₂SO₄ and LiOH respectively (by-product Li₂SO₄)

Figure 2 - Preparation of lithium hydroxide with bipolar membranes

Illustrative materials

锂盐转化制备(硫酸锂 → 氢氧化锂)
Diagram of lithium salt conversion preparation (lithium sulfate → lithium hydroxide)
锂盐转化制备(硫酸锂 → 氢氧化锂)
Diagram of lithium salt conversion preparation (lithium sulfate → lithium hydroxide)

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